Search results for "Wien effect"
showing 2 items of 2 documents
Electric field-assisted proton transfer and water dissociation at the junction of a fixed-charge bipolar membrane
1998
Abstract Electric field-enhanced (EFE) water dissociation can occur at the interfacial space charge junction of both biological and synthetic fixed-charge bipolar membranes. This dissociation has so far been analysed on an electrochemical basis using modified second Wien effect and absolute rate theories. We propose a statistical thermodynamics model to describe the cooperative orientation of the water molecules by the electric field at the bipolar junction. The approach is simple and retains some of the essential aspects of the phenomenon. In particular, the EFE water dissociation can now be rationalised on the basis of a field-assisted proton transfer mechanism involving the membrane fixe…
Model for ion transport in bipolar membranes.
1990
A simple theory for multi-ionic transport, nonequilibrium water dissociation, and space-charge effects in bipolar membranes is developed on the basis of some of the concepts used in the solid-state n-p junction. Ion transport is described in terms of the Nernst-Planck flux equation and nonequilibrium water dissociation is accounted for by the Onsager theory of the second Wien effect. The model is expected to be of interest for biological and synthetic membranes, and can explain a number of observed effects.